| Autor: |
VERA V. KRSTIC, GORDANA S. USCUMLIC, JASMINA B. NIKOLIC |
| Jazyk: |
angličtina |
| Rok vydání: |
2000 |
| Předmět: |
|
| Zdroj: |
Journal of the Serbian Chemical Society, Vol 65, Iss 5-6, Pp 353-359 (2000) |
| Druh dokumentu: |
article |
| ISSN: |
0352-5139 |
| Popis: |
The ultraviolet absorption spectra of cyclohex-1-enylcarboxylic acid and 2-methylcyclohex-1-enylcarboxylic acid were determined in six protic and nine aprotic solvents in the wavelength range from 200 to 400 nm. The position of the lmax of the two examined acids showed that the ultraviolet absorption maximums of cyclohex-1-enylcarboxylic acid were at consistently longer wavelengths in protic solvents than those of methylcyclohex-1-enylcarboxylic acid. The opposite was true in aprotic solvents. In order to explain the obtained results, the ultraviolet absorption frequencies of the electronic transitions in the carboxy carbonyl group of the examined acids were correlated using a total solvatochromic equation of the form: n = n0 + sp* + aa + bb, where p* is a measure of the solvent polarity, b represents the scale of solvent hydrogen bond acceptor basicities and a represents the scale of solvent hydrogen bond donor acidities. The correlation of the spectroscopic data was carried out by means of multiple linear regression analysis. The opposing solvent effects on the ultraviolet absorption maximums of the two examined acids were discussed. |
| Databáze: |
Directory of Open Access Journals |
| Externí odkaz: |
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