Mineral chemistry and alteration patterns of Cr-spinel in serpentinized peridotites from NW Iran

Autor: Mohssen Moazzen, Masoumeh Ahangari, Roland Oberhänsli, Uwe Altenberger
Jazyk: angličtina
Rok vydání: 2024
Předmět:
Zdroj: Journal of Asian Earth Sciences: X, Vol 11, Iss , Pp 100178- (2024)
Druh dokumentu: article
ISSN: 2590-0560
DOI: 10.1016/j.jaesx.2024.100178
Popis: The Late Cretaceous ophiolite mélange in the Salmas area of NW Iran is a part of the Neotethys ophiolites. The mélange includes serpentinized harzburgite, serpentinites, mafic rocks, radiolarite, layered red pelagic limestones and grey and white marbles. Harzburgite main primary mineral phases are olivine, orthopyroxene, clinopyroxene and Cr-spinel. Cr-spinel has Cr2O3 contents of 21.13 to 30.18 wt% and high Al2O3 (38.67–48.52 wt%), FeO (15.18–18.13 wt%) and MgO (15.18–17.51 wt%) contents. The 100 × Cr/(Cr + Al) ratios of 23 to 34 indicate 9 to 13 % partial melting in the Mid Ocean Ridge (MOR) environment for the origin of the peridotites. An alteration zone is developed around the altered Cr-spinel. Fine-grained minerals assemblage at the spinel crystals’ margin includes Cr-rich chlorite, Cr-rich garnet and spinel-silicate mixture. A 2–5 μm wide transitional zone is developed between the chromite-silicate assemblage and the Cr-rich garnet zone. The chemical variations of major oxides across the alteration zone are mainly diffusion controlled. Al, Cr and Mg have diffused out from the primary spinel and Fe and Mn have diffused into the spinel. Cr-spinel is altered in two stages due to serpentinization. During the first stage and following hydration, spinel reacted with olivine and orthopyroxene to form Cr-rich chlorite and ferrian chromite. Silica formed at this stage. At the second stage, the reaction between the chromite-silicate assemblage and Cr-rich chlorite plus silica form the first stage and Ca2+ in the fluid (released from clinopyroxene alteration) produced Cr-rich garnet and H2O-rich fluid, at temperature between 400 and 600 °C.
Databáze: Directory of Open Access Journals