Poly[bis(4,4′-bipyridine)(μ3-4,4′-dicarboxybiphenyl-3,3′-dicarboxylato)iron(II)]

Autor: Rong-Hua Zeng, Yi-Fan Luo, Han Lu, Hui-Ling Lai, Qun-Hui Meng
Jazyk: angličtina
Rok vydání: 2009
Předmět:
Zdroj: Acta Crystallographica Section E, Vol 65, Iss 12, Pp m1537-m1538 (2009)
Druh dokumentu: article
ISSN: 16005368
1600-5368
DOI: 10.1107/S1600536809046273
Popis: In the polymeric title complex, [Fe(C16H8O8)(C10H8N2)2]n, the iron(II) cation is coordinated by four O atoms from three different 4,4′-dicarboxybiphenyl-3,3′-dicarboxylate ligands and two N atoms from two 4,4′-bipyridine ligands in a distorted octahedral geometry. The 4,4′-dicarboxybiphenyl-3,3′-dicarboxylate ligands bridge adjacent cations, forming chains parallel to the c axis. The chains are further connected by intermolecular O—H...N hydrogen bonds, forming two-dimensional supramolecular layers parallel to (010).
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