A Combined Chemical-Electrochemical Process to Capture CO2 and Produce Hydrogen and Electricity

Autor: Nabila Shamim, Shuza Binzaid, Jorge Federico Gabitto, John Okyere Attia
Jazyk: angličtina
Rok vydání: 2021
Předmět:
Zdroj: Energies, Vol 14, Iss 18, p 5807 (2021)
Druh dokumentu: article
ISSN: 1996-1073
DOI: 10.3390/en14185807
Popis: Several carbon sequestration technologies have been proposed to utilize carbon dioxide (CO2) to produce energy and chemical compounds. However, feasible technologies have not been adopted due to the low efficiency conversion rate and high-energy requirements. Process intensification increases the process productivity and efficiency by combining chemical reactions and separation operations. In this work, we present a model of a chemical-electrochemical cyclical process that can capture carbon dioxide as a bicarbonate salt. The proposed process also produces hydrogen and electrical energy. Carbon capture is enhanced by the reaction at the cathode that displaces the equilibrium into bicarbonate production. Literature data show that the cyclic process can produce stable operation for long times by preserving ionic balance using a suitable ionic membrane that regulates ionic flows between the two half-cells. Numerical simulations have validated the proof of concept. The proposed process could serve as a novel CO2 sequestration technology while producing electrical energy and hydrogen.
Databáze: Directory of Open Access Journals
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