Visible-Light-Driven Photocatalytic Activity of Magnetic BiOBr/SrFe12O19 Nanosheets

Autor: Taiping Xie, Jiao Hu, Jun Yang, Chenglun Liu, Longjun Xu, Jiankang Wang, Yuan Peng, Songli Liu, Xiuyu Yin, Yuanzhen Lu
Jazyk: angličtina
Rok vydání: 2019
Předmět:
Zdroj: Nanomaterials, Vol 9, Iss 5, p 735 (2019)
Druh dokumentu: article
ISSN: 2079-4991
DOI: 10.3390/nano9050735
Popis: Magnetic BiOBr/SrFe12O19 nanosheets were successfully synthesized using the hydrothermal method. The as-prepared samples were characterized by X-ray diffraction (XRD), scanning electron microscope (SEM), transmission electron microscope (TEM), and UV-visible diffused reflectance spectra (UV-DRS), and the magnetic properties were tested using a vibration sample magnetometer (VSM). The as-produced composite with an irregular flaky-shaped aggregate possesses a good anti-demagnetization ability (Hc = 861.04 G) and a high photocatalytic efficiency. Under visible light (λ > 420 nm) and UV light-emitting diode (LED) irradiation, the photodegradation rates of Rhodamine B (RhB) using BiOBr/SrFe12O19 (5 wt %) (BOB/SFO-5) after 30 min of reaction were 97% and 98%, respectively, which were higher than that using BiOBr (87%). The degradation rate of RhB using the recovered BiOBr/5 wt % SrFe12O19 (marked as BOB/SFO-5) was still more than 85% in the fifth cycle, indicating the high stability of the composite catalyst. Meanwhile, after five cycles, the magnetic properties were still as stable as before. The radical-capture experiments proved that superoxide radicals and holes were main active species in the photocatalytic degradation of RhB.
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