Construção artesanal de um eletrodo íon seletivo a chumbo(II): uma alternativa para disciplinas experimentais Homemade construction of a lead(II) ion selective electrode: an alternative to experimental subjects

Autor: Jonatas Gomes da Silva, Arilson Lehmkuhl, Silvia Keli de Barros Alcanfor
Jazyk: English<br />Spanish; Castilian<br />Portuguese
Rok vydání: 2009
Předmět:
Zdroj: Química Nova, Vol 32, Iss 4, Pp 1055-1058 (2009)
Druh dokumentu: article
ISSN: 0100-4042
1678-7064
DOI: 10.1590/S0100-40422009000400039
Popis: This works proposes a homemade construction of a lead(II) ISE of solid membrane (Ag2S/PbS) to determine Pb2+ ions in potentiometric titrations, using damaged combined glass electrodes. This electrode can be constructed in teaching laboratories, using it as a learning tool related to the theoretical principle of ISE. The analytical curve obtained (y = 27.056x + 337.58; R = 0.996) was linear on the range of 1 x 10-5 to 1 mol L-1 and has presented a very close behavior of the Nernstian. The homemade ISE has presented a similar selectivity to the commercial electrodes, showing to be a good alternative to the experimental activities on teaching laboratories.
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