Thermodynamic Evaluation of Novel 1,2,4-Triazolium Alanine Ionic Liquids as Sustainable Heat-Transfer Media

Autor: Kunhao Liang, Haiyun Yao, Jing Qiao, Shan Gao, Mingji Zong, Fengshou Liu, Qili Yang, Lanju Liang, Dawei Fang
Jazyk: angličtina
Rok vydání: 2024
Předmět:
Zdroj: Molecules, Vol 29, Iss 22, p 5227 (2024)
Druh dokumentu: article
ISSN: 1420-3049
DOI: 10.3390/molecules29225227
Popis: Ionic liquids, which are widely recognized as environmentally friendly solvents, stand out as promising alternatives to traditional heat-transfer fluids due to their outstanding heat-storage and heat-transfer capabilities. In the course of our ongoing research, we successfully synthesized ionic liquids 1-ethyl-4-alkyl-1,2,4-triazolium alanine [Taz(2,n)][Ala], where (n = 4, 5); in this study, we present comprehensive data on their density, surface tension, isobaric molar heat capacity, and thermal conductivity for the first time. The key thermophysical parameters influencing the heat-transfer process, such as thermal expansibility, compressibility, isochoric heat capacity, and heat-storage density, were meticulously calculated from experimental data. Upon comparison with previously reported ionic liquids and commercially utilized heat-transfer fluids, [Taz(2,n)][Ala] demonstrated superior heat-storage and heat-transfer performance, particularly in terms of heat-storage density (~2.63 MJ·m−3·K−1), thermal conductivity (~0.190 W·m−1·K−1), and melting temperature (~226 K). Additionally, the presence of the alanine anion in [Taz(2,n)][Ala] provides more possibilities for its functional application.
Databáze: Directory of Open Access Journals