New platinum(II) complexes of cycloalkanespiro-5-(2-thiohydantoins). Synthesis and quantum chemical investigation

Autor:	Petja E. Marinova, Marin Marinov, Vassil Delchev, Neyko Stoyanov
Jazyk:	angličtina
Rok vydání:	2015
Předmět:	cyclohexanespiro-5-(2-thiohydantoin) cycloheptanespiro-5-(2-thiohydantoin) DFT calculations metal complexes Chemistry QD1-999
Zdroj:	Acta Chimica Slovenica, Vol 62, Iss 1, Pp 225-232 (2015)
Druh dokumentu:	article
ISSN:	1318-0207 1580-3155
DOI:	10.17344/acsi.2014.1206
Popis:	Synthesis and characterization of new Pt(II) complexes of cyclohexanespiro-5-(2-thiohydantoin) (L1) and cycloheptanespiro-5-(2-thiohydantoin) (L2) are discussed. The new complexes are studied by elemental analysis, IR, ATR FTIR spectroscopy. The free ligands are investigated by UV-Vis, FT-IR ATR and Raman spectroscopy. The ground-state equilibrium geometries of the ligands L1 and L2 and their complexes with Pt(II) are optimized at the BLYP/CEP-31G theoretical level.
Databáze:	Directory of Open Access Journals
Externí odkaz:	https://doaj.org/article/472255ac9153483cafaf5efee03dfcc7 Zobrazit plný text záznamu View record in DOAJ Plný text ve formátu PDF