Strain-induced enhancement of the thermoelectric power in thin films of hole-doped La2NiO4+δ

Autor: P. L. Bach, J. M. Vila-Fungueiriño, V. Leborán, Elías Ferreiro-Vila, B. Rodríguez-González, F. Rivadulla
Jazyk: angličtina
Rok vydání: 2013
Předmět:
Zdroj: APL Materials, Vol 1, Iss 2, Pp 021101-021101 (2013)
Druh dokumentu: article
ISSN: 2166-532X
DOI: 10.1063/1.4818356
Popis: We propose a novel route for optimizing the thermoelectric power of a polaronic conductor, independent of its electronic conductivity. This mechanism is exemplified here in thin-films of La2NiO4+δ. Tensile stress induced by epitaxial growth on SrTiO3 doubles the thermoelectric power of ≈15 nm thick films relative to ≈90 nm films, while the electronic conductivity remains practically unchanged. Epitaxial strain influences the statistical contribution to the high temperature thermopower, but introduces a smaller correction to the electronic conductivity. This mechanism provides a new way for optimizing the high temperature thermoelectric performance of polaronic conductors.
Databáze: Directory of Open Access Journals