A Facile Procedure for the Conversion of Oximes to Ketones and Aldehydes with Potassium Dichromate in Dimethylformamide under Homogeneous Conditions

Autor: Li-Hong Huang, Ji-Dong Lou, Changhe Zhang, Fang Lin, Xiao-Nan Zou
Jazyk: angličtina
Rok vydání: 2012
Předmět:
Zdroj: E-Journal of Chemistry, Vol 9, Iss 4, Pp 2141-2144 (2012)
Druh dokumentu: article
ISSN: 0973-4945
2090-9810
DOI: 10.1155/2012/826527
Popis: Oxidative cleavage of oximes to their parent corresponding carbonyl compounds using potassium dichromate-dimethylformamide system under homogeneous conditions in good yields is described. The main advantage of the present method is no need of preparation of hexavalent chromium-based reagents due to using a polar aprotic solvent.
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