trans-Diaquabis(ethylenediamine-κ2N,N′)copper(II) bis[3-(3-pyridyl)propionate] dihydrate
| Autor: | Koman Marian, Andreas Fischer, Dušan Mikloš, Peter Segľa, Jan Moncol |
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| Jazyk: | angličtina |
| Rok vydání: | 2008 |
| Předmět: | |
| Zdroj: | Acta Crystallographica Section E, Vol 64, Iss 4, Pp m509-m510 (2008) |
| Druh dokumentu: | article |
| ISSN: | 16005368 1600-5368 |
| DOI: | 10.1107/S1600536808005400 |
| Popis: | The asymmetric unit of the title complex, [Cu(C2H8N2)2(H2O)2](C8H8NO2)2·2H2O, contains one anion, one half-cation and one water molecule. The CuII atom in the [Cu(en)2(H2O)2]2+ cation (en is ethylenediamine) lies on an inversion centre. The four N atoms of the en ligands in the equatorial plane around the CuII atom form a slightly distorted square-planar arrangement, while the slightly distorted Jahn–Teller octahedral coordination is completed by two water O atoms in axial positions. In the crystal structure, intra- and intermolecular N—H...O and O—H...O hydrogen bonds form a three-dimensional network. |
| Databáze: | Directory of Open Access Journals |
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