Tris(thiocyanato-κN)tris(triphenylphosphine oxide-κO)europium(III)–(nitrato-κ2O,O′)bis(thiocyanato-κN)tris(triphenylphosphine oxide-κO)europium(III) (1/1)
| Autor: | Anthony T. Thames, Frankie D. White, Lam N. Pham, Kang Rui Xiang, Richard E. Sykora |
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| Jazyk: | angličtina |
| Rok vydání: | 2012 |
| Předmět: | |
| Zdroj: | Acta Crystallographica Section E, Vol 68, Iss 12, Pp m1530-m1530 (2012) |
| Druh dokumentu: | article |
| ISSN: | 16005368 1600-5368 |
| DOI: | 10.1107/S1600536812047472 |
| Popis: | The title co-crystal, [Eu(NCS)3(C18H15OP)3][Eu(NCS)2(NO3)(C18H15OP)3], contains two distinct neutral complexes. Each complex has threefold symmetry about its central Eu3+ ion. As a result, the nitrate-containing molecule contains disorder of its bidentate nitrate and two N-bound thiocyanate anions, while the [Eu(NCS)3(OPPh3)3] complex is fully ordered. There is a weak π–π stacking interaction between the phenyl rings of the two molecules [centroid–centroid distance = 4.138 (4) Å]. |
| Databáze: | Directory of Open Access Journals |
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