Bis(μ2-benzoato-κ2O:O′)bis[(benzoato-κ2O,O′)bis(4,4′-bipyridine-κN)cobalt(II)]–benzoic acid (1/6)
| Autor: | Rodolfo Peña-Rodríguez, José María Rivera, Raúl Colorado-Peralta, Angélica María Duarte-Hernández, Angelina Flores-Parra |
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| Jazyk: | angličtina |
| Rok vydání: | 2014 |
| Předmět: | |
| Zdroj: | Acta Crystallographica Section E, Vol 70, Iss 1, Pp m21-m22 (2014) |
| Druh dokumentu: | article |
| ISSN: | 1600-5368 16005368 |
| DOI: | 10.1107/S1600536813033357 |
| Popis: | In the title compound, [Co2(C7H5O2)4(C10H8N2)4]·6C6H5COOH, the centrosymmetric cobalt dimer co-crystallizes with six molecules of benzoic acid. Each CoII atom is coordinated by four O atoms in a distorted square-planar arrangement while the N atoms are located in apical positions. The dihedral angles between the rings comprising each of the 4,4′-bipyridyl ligands are 25.2 (2) and 22.8 (2)°. In the crystal, the three-dimensional network is assembled by O—H...O and C—H...O hydrogen bonds. |
| Databáze: | Directory of Open Access Journals |
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