Stereospecific ligands and their complexes. Synthesis and characterization of the s-cis-K[Ru(S,S-eddp)Cl2]∙3H2O

Autor: VERICA V. GLODJOVIC, SRECKO R. TRIFUNOVIC
Jazyk: angličtina
Rok vydání: 2008
Předmět:
Zdroj: Journal of the Serbian Chemical Society, Vol 73, Iss 5, Pp 541-545 (2008)
Druh dokumentu: article
ISSN: 0352-5139
Popis: In the reaction of ruthenium(III) chloride and an edda-like ligand ethylenediamine-N,N'-di-S,S-2-propionic acid (S,S-eddp) in aqueous solution led to the formation of only one of the three possible geometrical isomers potassium-s-cis-dichlorido-(ethylenediamine-N,N'-di-S,S-2-propionato)-ruthenate(III)--trihydrate, s-cis-K[Ru(S,S-eddp)Cl2]∙3H2O. The assumed geometry of the complex was based on its electronic absorption and infrared spectra.
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