Quasi-Periodic Noise Oscillations in Oxyhydrates of Rare-Earth Elements

Autor: Y. I. Sucharev, B. A. Markov, T. I. Prolubnikova, I. I. Lebedeva
Jazyk: angličtina
Rok vydání: 2012
Předmět:
Zdroj: Eurasian Chemico-Technological Journal, Vol 14, Iss 1, Pp 61-72 (2012)
Druh dokumentu: article
ISSN: 1562-3920
2522-4867
DOI: 10.18321/ectj101
Popis: The present paper dwells upon the chemical foundations of formation of a gel nanostructure (by the example of zirconium oxyhydrate) at the time of formation of oxyhydrate polymer chain and develops electrophoretic (diffusional) conceptions related to the phenomenon of self-organization of nonequilibrium oxyhydrate gel. Adduced are the experimental data (measurements of spontaneous current induced by the alterations in capacity of the polarized double electrical layer of the gel) that permit to claim that the mathematical model of the phenomenon is not in contradiction with the experiment. On the ground of the experimental data and calculations it is concluded that the constant magnetic field alters the character of geometrical configuration of chemical interaction of the oxyhydrate gel fragments with each other, which affects the value of nano-current measured in the course of the experiment.
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