| Autor: |
Mengting Chen, Qifeng Zhong, Meihua Zhang, Hao Huang, Yingxin Liu, Zuojun Wei |
| Jazyk: |
angličtina |
| Rok vydání: |
2022 |
| Předmět: |
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| Zdroj: |
Catalysis Communications, Vol 172, Iss , Pp 106550- (2022) |
| Druh dokumentu: |
article |
| ISSN: |
1873-3905 |
| DOI: |
10.1016/j.catcom.2022.106550 |
| Popis: |
Herein, RuMn/Al2O3-SiO2 multifunctional catalyst was prepared and efficiently converted lignin-derived phenols into cyclohexanol by aqueous partial hydrodeoxygenation (HDO). The optimal RuMn/Al2O3-SiO2 (Ru/Mn = 2) catalyst achieved 96.8% of cyclohexanol yield with 100% guaiacol conversion under mild reaction conditions (180 °C and 2.0 MPa H2) for 4 h, with a turnover frequency (TOF) of 861.1 h−1, which is better than most results reported. The high performance of RuMn/Al2O3-SiO2 was attributed to the synergic effect of highly dispersed Ru nanoparticles with small size (1.25 nm), the microsphere structure, the appropriate acid sites from Al2O3-SiO2 and acid-base sites from MnOx. |
| Databáze: |
Directory of Open Access Journals |
| Externí odkaz: |
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