4,6-Dimethyl-2-thioxo-1,2-dihydropyrimidin-3-ium chloride–thiourea (1/1)
| Autor: | Papa Aly Gaye, Aliou Hamady Barry, Mohamed Gaye, Aminata Diasse Sarr, Abdou Salam Sall |
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| Jazyk: | angličtina |
| Rok vydání: | 2009 |
| Předmět: | |
| Zdroj: | Acta Crystallographica Section E, Vol 65, Iss 6, Pp o1252-o1252 (2009) |
| Druh dokumentu: | article |
| ISSN: | 16005368 1600-5368 |
| DOI: | 10.1107/S1600536809016857 |
| Popis: | In the title compound, C6H9N2S+·Cl−·CH4N2S, the 4,6-dimethyl-2-thioxo-1,2-dihydropyrimidin-3-ium cation is protonated at one of the pyrimidine N atoms. The cations are bridged by the chloride anions through a pair of N—H...Cl hydrogen bonds. The amino groups of each thiourea adduct interact with the chloride anions through a pair of N—H...Cl hydrogen bonds and the S atom of another thiourea adduct through a pair of N—H...S hydrogen bonds. These interactions result in a layered hydrogen-bonded network propagating parallel to the bc plane. Except for two H atoms, all atoms are on special positions. |
| Databáze: | Directory of Open Access Journals |
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