A New BEDT-TTF-Based Organic Charge Transfer Salt with a New Anionic Strong Acceptor, N,N'-Disulfo-1,4-benzoquinonediimine
Autor: | Scott S. Turner, Shin’ichi Nakatsuji, Jun-ichi Yamada, Hiroki Akutsu |
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Jazyk: | angličtina |
Rok vydání: | 2012 |
Předmět: | |
Zdroj: | Crystals, Vol 2, Iss 2, Pp 182-192 (2012) |
Druh dokumentu: | article |
ISSN: | 2073-4352 |
DOI: | 10.3390/cryst2020182 |
Popis: | A novel organic dianion, N,N'-Disulfo-1,4-benzoquinonediimine (1) has been prepared, which is a strong electron acceptor. The reduction potential of the PPh4 salt indicates that 1 is a stronger acceptor than DDQ (2,3-dichloro-5,6-dicyano-1,4-benzoquinone). The dianionic acceptor provided a BEDT-TTF salt, (BEDT-TTF)41·3H2O, the structures and physical properties of which are reported. |
Databáze: | Directory of Open Access Journals |
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