A New BEDT-TTF-Based Organic Charge Transfer Salt with a New Anionic Strong Acceptor, N,N'-Disulfo-1,4-benzoquinonediimine

Autor: Scott S. Turner, Shin’ichi Nakatsuji, Jun-ichi Yamada, Hiroki Akutsu
Jazyk: angličtina
Rok vydání: 2012
Předmět:
Zdroj: Crystals, Vol 2, Iss 2, Pp 182-192 (2012)
Druh dokumentu: article
ISSN: 2073-4352
DOI: 10.3390/cryst2020182
Popis: A novel organic dianion, N,N'-Disulfo-1,4-benzoquinonediimine (1) has been prepared, which is a strong electron acceptor. The reduction potential of the PPh4 salt indicates that 1 is a stronger acceptor than DDQ (2,3-dichloro-5,6-dicyano-1,4-benzoquinone). The dianionic acceptor provided a BEDT-TTF salt, (BEDT-TTF)41·3H2O, the structures and physical properties of which are reported.
Databáze: Directory of Open Access Journals