Sulfated polyborate as Bronsted acid catalyst for Knoevenagel condensation

Autor: Prerna Ganwir, Priyanka Bandivadekar, Ganesh Chaturbhuj
Jazyk: angličtina
Rok vydání: 2022
Předmět:
Zdroj: Results in Chemistry, Vol 4, Iss , Pp 100632- (2022)
Druh dokumentu: article
ISSN: 2211-7156
DOI: 10.1016/j.rechem.2022.100632
Popis: We have developed the use of Bronsted acid for Knoevenagel condensation. Sulfated polyborate has been used for efficient Knoevenagel condensation of aromatic, heterocyclic, α,β-unsaturated, and aliphatic aldehydes in the ecologically friendly ethanol: water (1:1) mixture as solvent at 70 °C. It took less time for certain aldehydes to react with active methylenes. The present method demonstrated significant benefits in terms of first-time use of Bronsted acid catalyst, mild reaction conditions, and better product yields.
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