| Autor: |
Zhaoyang Yin, Zhenxin Yi, Yongxing Tang, Hao Wei, Wei Huang |
| Jazyk: |
angličtina |
| Rok vydání: |
2023 |
| Předmět: |
|
| Zdroj: |
FirePhysChem, Vol 3, Iss 2, Pp 135-141 (2023) |
| Druh dokumentu: |
article |
| ISSN: |
2667-1344 |
| DOI: |
10.1016/j.fpc.2022.11.004 |
| Popis: |
Azo-bridged FOX-7 derivatives with ultra-high theoretical detonation performance were seen as potential high-performance energetic materials. So far, most of the researches were focused on the diverse oxidation reactions involving 1,1-diamino-2,2-dinitroethene (FOX-7) as a starting material, which usually results in undesirable products. In this paper, by replacing the starting substrate from FOX-7 to its analogous 1,1-diamino-2-nitro-2-(1-amino-1H-tetrazol-5-yl) ethene (1), three unexpected halogenated-substituted compounds (2-4) were obtained rather than the anticipated azo-bridged products. The crystal structures of 2-4 were fully determined by single-crystal X-ray diffraction. The reaction mechanism and physicochemical properties to them were deeply investigated. 4 shows good detonation performance (Dv = 7554 m/s, P = 24.3 GPa), which are superior to these of TNT (Dv = 6881 m/s, P = 19.5 GPa). The methodology may be helpful for the exploration of azo-bridged FOX-7 compounds in the future. |
| Databáze: |
Directory of Open Access Journals |
| Externí odkaz: |
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