| Autor: |
Yingying Guo, Donghai Wu, Minhan Li, Kaixi Wang, Shouren Zhang, Guangli He, Hengbo Yin, Chenyu Huang, Baocheng Yang, Jianan Zhang |
| Jazyk: |
angličtina |
| Rok vydání: |
2022 |
| Předmět: |
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| Zdroj: |
Small Science, Vol 2, Iss 10, Pp n/a-n/a (2022) |
| Druh dokumentu: |
article |
| ISSN: |
2688-4046 |
| DOI: |
10.1002/smsc.202200035 |
| Popis: |
The lack of highly efficient, inexpensive catalysts severely hinders the large‐scale application of electrochemical energy conversion technologies (e.g., electrochemical hydrogen evolution reaction (HER) for hydrogen production, metal–air batteries (Cathode: oxygen reduction reaction (ORR))). As a new class of nanomaterials with a high ratio of surface atoms and tunable composition and electronic structure, metal nanocluster (NCs) are promising candidates as catalysts. Herein, a novel catalyst using S,N‐doped carbon matrix (NSCSs) is synthesized to efficiently stabilize high density and ultra‐uniform ruthenium (Ru) nanoclusters (Ru@NSCSs) by small‐molecule self‐assembly pyrolysis approach. The obtained Ru@NSCSs catalyst exhibits outstanding HER activity in all pH conditions (especially with a low overpotential of 5 mV at a current density of 10 mA cm−2 in 1 m KOH) and excellent ORR performance (half‐wave potential (E 1/2) of 0.854 V in 0.1 m KOH). Based on the experimental investigations and theoretical calculations, it is discovered that the S‐atom can modulate the electronic structure and optimization of redox states on the surficial sites of Ru NCs during the ORR process. This work provides a feasible strategy for understanding and regulating the metal–support interface of ultra‐uniform nanoclusters catalysts. |
| Databáze: |
Directory of Open Access Journals |
| Externí odkaz: |
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