| Autor: |
Nadezhda S. Tsvetkova, Dmitry A. Malyshkin, Ivan L. Ivanov, Dmitry S. Tsvetkov, Andrey Yu. Zuev |
| Jazyk: |
angličtina |
| Rok vydání: |
2023 |
| Předmět: |
|
| Zdroj: |
Energies, Vol 16, Iss 7, p 2980 (2023) |
| Druh dokumentu: |
article |
| ISSN: |
1996-1073 |
| DOI: |
10.3390/en16072980 |
| Popis: |
Chemical compatibility and cation interdiffusion between the double perovskite cobaltites RBaCo2O6−δ (R = Gd, Pr) and proton-conducting electrolyte BaZr0.8Y0.2O3−δ were studied. Chemical interaction was found to occur already at 1100 °C as a result of the partial dissolution of RBaCo2O6−δ (R = Gd, Pr) in BaZr0.8Y0.2O3−δ. Analysis of the element distribution along the cross sections of diffusion couples RBaCo2O6−δ(R = Gd, Pr)|BaZr0.8Y0.2O3−δ showed strong interdiffusion of cations, with cobalt being the most mobile one. Its diffusion depth in the electrolyte reaches up to several hundreds of micrometers. The addition of NiO as a sintering aid to BaZr0.8Y0.2O3−δ promotes cation diffusion especially through the grain boundary mechanism, increasing the diffusion depth of Co. The possible implications of cation interdiffusion on the performance of proton-conducting SOFCs are discussed based on the results obtained. |
| Databáze: |
Directory of Open Access Journals |
| Externí odkaz: |
|
|
Nepřihlášeným uživatelům se plný text nezobrazuje |
K zobrazení výsledku je třeba se přihlásit.
|
