Influence of Pyrolysis Temperature on Biochar Produced from Lignin–Rich Biorefinery Residue

Autor: Corinna Maria Grottola, Paola Giudicianni, Fernando Stanzione, Raffaele Ragucci
Jazyk: angličtina
Rok vydání: 2022
Předmět:
Zdroj: ChemEngineering, Vol 6, Iss 5, p 76 (2022)
Druh dokumentu: article
ISSN: 2305-7084
DOI: 10.3390/chemengineering6050076
Popis: The biorefinery concept is growing rapidly for bio-based production of fuels and products, and steam explosion is by far the most applied pre-treatment technology allowing the delignification of lignocellulosic biomass. Within the bioethanol production process, pyrolysis of lignin-rich residue (LRR), for producing char to be used in a wide variety of applications, presents a viable way to recover materials and energy, helping to improve the sustainability of the whole production chain. In the present study, it is shown that yields, elemental composition and porosity characteristics of LLR-char are significantly different from those of char produced from alkali lignin. Both products yields and char composition were more similar to the typical values of woody and herbaceous biomasses. The chemical characterization of the chars’ organic matrices as well as the content of the main inorganic species suggest the opportunity to perform pyrolysis at low temperatures for producing high yields of chars suitable to be used as carbon sink or soil fertilizers. The BET values of the chars obtained at final temperatures in the range 500–700 °C seem to be promising for char-application processes involving surface phenomena (e.g., adsorption, catalyst support), thus encouraging further analyses of char-surface chemistry.
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