One-Pot Synthesis of TiO2/Hectorite Composite and Its Photocatalytic Degradation of Methylene Blue

Autor: Dingqing Yang, Jinyang Chen, Xiaomin Hong, Jingying Cui, Lingzhen Li
Jazyk: angličtina
Rok vydání: 2022
Předmět:
Zdroj: Catalysts, Vol 12, Iss 3, p 297 (2022)
Druh dokumentu: article
ISSN: 2073-4344
DOI: 10.3390/catal12030297
Popis: TiO2/hectorite composite photocatalysts with different molar ratios of lithium, magnesium, and silicon were synthesized by a one-pot hydrothermal method. The samples were characterized by X-ray diffraction (XRD), Fourier transform infrared (FTIR) spectroscopy, scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), N2 adsorption-desorption isotherms, and ultraviolet-visible diffuse reflectance spectra (UV-Vis DRS). When the molar ratio of lithium, magnesium, and silicon was 1.32:5.34:8 (TH-2), the composite showed the highest UV photocatalytic degradation of methylene blue (MB). The apparent rate constant of TH-2 was 0.04361 min−1, which was about 3.12 times that of EVONIK Degussa commercial TiO2 of AEROXIDE P25. The improvement of photocatalytic efficiency of the composite was mainly due to its high specific surface area, light trapping ability, and effective separation of electrons (e−) and holes (h+). At the same time, the F element of hectorite is beneficial to the formation of Ti3+ in TiO2, thus enhancing the photocatalytic activity. After five cycles, the removal rate of MB with TH-2 still reached 87.9%, indicating its excellent reusability.
Databáze: Directory of Open Access Journals
Nepřihlášeným uživatelům se plný text nezobrazuje