Autor: |
Zhang Wen-Juan, Ding Ye-Zhi, Wang Ya-Xian, Wang You-Liang, Fei Yu-Long, Ran Meng-Yu |
Jazyk: |
angličtina |
Rok vydání: |
2023 |
Předmět: |
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Zdroj: |
Nanotechnology Reviews, Vol 12, Iss 1, Pp 57-78 (2023) |
Druh dokumentu: |
article |
ISSN: |
2191-9097 |
DOI: |
10.1515/ntrev-2023-0114 |
Popis: |
The pollution of silver ion (Ag(i)) has become a serious environmental threat and hazard to ecosystem and human health. Thus, the nanoscale zero valent iron (nZVI)-doped polypyrrole-based carbon nanotube (nZVI/CNT) composites were synthesized by a facile method to remove Ag(i) from wastewater due to the toxicity and scarcity nature of Ag(i). In this process, Fe3+ initiated the self-assembly of polypyrrole tubes in the presence of methyl orange, while it also served as an iron source generated nZVI/CNTs by carbothermal reduction method. The nZVI/CNT composites exhibited a homogeneous tubular structure, and the nZVI formed were uniformly dispersed in the nZVI/CNT composites. The nZVI/CNT composites were used as an adsorbent for the removal of Ag(i) and showed a higher adsorption capacity compared to nZVI and CNTs, with a maximum adsorption capacity of 522.41 mg g−1. Ag(i) was adsorbed on nZVI/CNT composites by ion exchange and chelation, where Ag(i) was reduced to non-toxic Ag due to the redox reaction among pyrrolic-N, nZVI, and Ag(i). The adsorption process of Ag(i) on nZVI/CNT composites was dominated by monolayer adsorption. According to our results, nZVI/CNT composites can be used as economical treatment for wastewater containing Ag(i). |
Databáze: |
Directory of Open Access Journals |
Externí odkaz: |
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