SSZ-13 supported Ir as an efficient catalyst for methylcyclopentane ring-opening reaction

Autor: Peng Shan, Panpan Niu, Huifang Zhang, Chuanhao Zhang, Ningyue Lu, Yan Wang, Binbin Fan, Ruifeng Li
Jazyk: angličtina
Rok vydání: 2021
Předmět:
Zdroj: Catalysis Communications, Vol 154, Iss , Pp 106311- (2021)
Druh dokumentu: article
ISSN: 1873-3905
35831421
DOI: 10.1016/j.catcom.2021.106311
Popis: Ir/H-SSZ-13 catalysts were used for methylcyclopentane (MCP) ring-opening (RO) reaction, and exhibit higher yields to RO products than H-ZSM-5, H-USY and Al2O3 supported Ir catalysts. Ir species supported on H-SSZ-13-A (about 200 nm) exhibits higher activity than those on H-SSZ-13-B (about 8 μm) due to its more accessible acid sites. Ir/H-SSZ-13-A gives higher reactivity than Ir/Al2O3, especially in the case of low Ir loading because of the promotion of the strong acid sites located on the external surface of H-SSZ-13-A. This work demonstrates that SSZ-13 supported metal is a potential catalyst for RO reaction.
Databáze: Directory of Open Access Journals
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