A Model of a Two-step Three-electron Surface Redox Reaction

Autor:	Milivoj Lovrić
Jazyk:	English<br />Croatian
Rok vydání:	2024
Předmět:	two-step electron transfers surface-confined electrode reaction cyclic voltammetry successive electrode reactions theoretical model Chemistry QD1-999
Zdroj:	Kemija u Industriji, Vol 73, Iss 5-6, Pp 221-227 (2024)
Druh dokumentu:	article
ISSN:	0022-9830 1334-9090
DOI:	10.15255/KUI.2023.041
Popis:	A theory of a two-step surface redox mechanism, involving both single-electron and two-electron transfers, is developed for cyclic voltammetry. It is assumed that the first step is kinetically controlled, while the second one is reversible. Depending on the difference in standard potentials, three types of responses appear as functions of the kinetic parameters. Calculation of the transfer coefficients and the standard rate constant is explained.
Databáze:	Directory of Open Access Journals
Externí odkaz:	https://doaj.org/article/3ea704ac6c39490e91d0a8caa2d41a9c Zobrazit plný text záznamu View record in DOAJ Plný text ve formátu PDF