trans-Bis[2-(piperazin-1-yl)ethanamine]bis(saccharinato)cobalt(II)
| Autor: | Veysel T. Yilmaz, Serkan Guney, Canan Kazak |
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| Jazyk: | angličtina |
| Rok vydání: | 2008 |
| Předmět: | |
| Zdroj: | Acta Crystallographica Section E, Vol 64, Iss 1, Pp m59-m60 (2008) |
| Druh dokumentu: | article |
| ISSN: | 16005368 1600-5368 |
| DOI: | 10.1107/S1600536807062745 |
| Popis: | In the centrosymmetric title complex, [Co(C7H4NO3S)2(C6H15N3)2], the CoII ion is coordinated by two saccharinate (sac) anions and two neutral 2-piperazin-1-ylethanamine (ppzea) ligands, showing a distorted octahedral coordination. Sac is O-bonded via the carbonyl group, while ppzea acts as an N,N′-bidentate chelating ligand. The molecules are connected by N—H...N and N—H...O hydrogen bonds, forming a linear chain running parallel to the crystallographic a axis. The compound is isostructural with the reported Ni, Zn, and Cd analogues. |
| Databáze: | Directory of Open Access Journals |
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