| Autor: |
Hae-Jun Kwon, Sang-Wook Woo, Yong-Ju Lee, Je-Young Kim, Sung-Man Lee |
| Jazyk: |
angličtina |
| Rok vydání: |
2021 |
| Předmět: |
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| Zdroj: |
Energies, Vol 14, Iss 7, p 1946 (2021) |
| Druh dokumentu: |
article |
| ISSN: |
1996-1073 |
| DOI: |
10.3390/en14071946 |
| Popis: |
The electrochemical performance of modified natural graphite (MNG) and artificial graphite (AG) was investigated as a function of electrode density ranging from 1.55 to 1.7 g∙cm−3. The best performance was obtained at 1.55 g∙cm−3 and 1.60 g∙cm−3 for the AG and MNG electrodes, respectively. Both AG, at a density of 1.55 g∙cm−3, and MNG, at a density of 1.60 g∙cm−3, showed quite similar performance with regard to cycling stability and coulombic efficiency during cycling at 30 and 45 °C, while the MNG electrodes at a density of 1.60 g∙cm−3 and 1.7 g∙cm−3 showed better rate performance than the AG electrodes at a density of 1.55 g∙cm−3. The superior rate capability of MNG electrodes can be explained by the following effects: first, their spherical morphology and higher electrode density led to enhanced electrical conductivity. Second, for the MNG sample, favorable electrode tortuosity was retained and thus Li+ transport in the electrode pore was not significantly affected, even at high electrode densities of 1.60 g∙cm−3 and 1.7 g∙cm−3. MNG electrodes also exhibited a similar electrochemical swelling behavior to the AG electrodes. |
| Databáze: |
Directory of Open Access Journals |
| Externí odkaz: |
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