| Autor: |
Kwang-Mo Kang, Seok-Han Lee, Sang-Youn Kim, Yoon-Chae Nah |
| Jazyk: |
angličtina |
| Rok vydání: |
2024 |
| Předmět: |
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| Zdroj: |
Electrochemistry Communications, Vol 169, Iss , Pp 107833- (2024) |
| Druh dokumentu: |
article |
| ISSN: |
1388-2481 |
| DOI: |
10.1016/j.elecom.2024.107833 |
| Popis: |
Anodization enables nano-structure fabrication through electrochemical parameter control. While various approaches exist for creating localized or patterned oxide layers, many are complex and time-consuming. This study adopted a commercial 3D printer for high-speed (1 mm/s) anodization, forming TiO2 nanotube layers on Ti substrates in G-code-designed patterns. Comprehensive characterization using XRD, SEM, XPS, and simulated electric field distribution analysis revealed well-defined nanostructures and provided insights into the formation mechanism. Furthermore, viologen-anchored TiO2 showed significantly improved electrochromic performance compared to pristine TiO2, with a higher reflectance difference (46.2% vs. 6.85%). This 3D printing-anodization hybrid method offers a rapid approach to fabricating patterned TiO2 nanostructures, showing promise for electrochromic devices with enhanced optical modulation capabilities. |
| Databáze: |
Directory of Open Access Journals |
| Externí odkaz: |
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Full Text from ScienceDirect