Colorimetric detection of hydrogen peroxide by dioxido-vanadium(V) complex containing hydrazone ligand: synthesis and crystal structure

Autor: Sunshine D. Kurbah, Ibanphylla Syiemlieh, Ram A. Lal
Jazyk: angličtina
Rok vydání: 2018
Předmět:
Zdroj: Royal Society Open Science, Vol 5, Iss 3 (2018)
Druh dokumentu: article
ISSN: 2054-5703
DOI: 10.1098/rsos.171471
Popis: Dioxido-vanadium(V) complex has been synthesized in good yield, the complex was characterized by IR, UV–visible and 1H NMR spectroscopy. Single crystal X-ray crystallography techniques were used to assign the structure of the complex. Complex crystallized with monoclinic P21/c space group with cell parameters a (Å) = 39.516(5), b (Å) = 6.2571(11), c (Å) = 17.424(2), α (°) = 90, β (°) = 102.668(12) and γ (°) = 90. The hydrazone ligand is coordinate to metal ion in tridentate fashion through –ONO– donor atoms forming a distorted square pyramidal geometry around the metal ion.
Databáze: Directory of Open Access Journals