Dichlorido{1-[N-(5-chloro-2-oxidophenyl)carboximidoyl]naphthalen-2-olato-κ3O,N,O′}(methanol-κO)tin(IV)
| Autor: | Babak Mirtamizdoust, Edward R. T. Tiekink, Gholam Hossein Shahverdizadeh, Seik Weng Ng |
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| Jazyk: | angličtina |
| Rok vydání: | 2012 |
| Předmět: | |
| Zdroj: | Acta Crystallographica Section E, Vol 68, Iss 3, Pp m246-m247 (2012) |
| Druh dokumentu: | article |
| ISSN: | 16005368 1600-5368 |
| DOI: | 10.1107/S160053681200390X |
| Popis: | In the title complex, [Sn(C17H10ClNO2)Cl2(CH3OH)], the SnIV atom features a distorted octahedral geometry defined by the O,N,O′-donors of the dianion, two Cl atoms and the methanol O atom. The six-membered chelate ring has a half-chair conformation with the Sn atom lying 0.449 (4) Å out of the plane defined by the remaining atoms (r.m.s. deviation = 0.0238 Å). Supramolecular helical chains along [100], mediated by O—H...O hydrogen bonds, feature in the crystal packing. Chains are linked by C—H...O, C—H...Cl and π–π [centroid–centroid distance = 3.598 (2) Å] interactions. |
| Databáze: | Directory of Open Access Journals |
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