Excimer Laser Induced Spatially Resolved Formation and Implantation of Plasmonic Particles in Glass

Autor: Maximilian Heinz, Jörg Meinertz, Manfred Dubiel, Jürgen Ihlemann
Jazyk: angličtina
Rok vydání: 2018
Předmět:
Zdroj: Nanomaterials, Vol 8, Iss 12, p 1035 (2018)
Druh dokumentu: article
ISSN: 2079-4991
DOI: 10.3390/nano8121035
Popis: Metallic nanoparticles are important building blocks for plasmonic applications. The spatially defined arrangement of these nanoparticles in a stable glass matrix is obtained here by nanosecond excimer laser irradiation at 193 nm. Two approaches are addressed: (1) Laser induced formation of particles from a dopant material pre-incorporated in the glass, (2) Particle formation and implantation by irradiation of material pre-coated on top of the glass. Silver nanoparticles are formed inside Ag+ doped glass (method 1). Gold nanoparticles are implanted by irradiation of gold coated glass (method 2). In the latter case, with a few laser pulses the original gold film disintegrates into particles which are then embedded in the softened glass matrix. A micron sized spatial resolution (periodic arrangements with 2 µm period) is obtained in both cases by irradiating the samples with an interference beam pattern generated by a phase mask. The plasmonic absorption of the nanoparticles leads to a contrast of the optical density between irradiated and non-irradiated lines of up to 0.6.
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