Dichlorido{N′-[phenyl(pyridin-2-yl-κN)methylidene]isonicotinohydrazide-κ2N′,O}zinc
| Autor: | Adama Sy, Moussa Dieng, Ibrahima Elhadj Thiam, Mohamed Gaye, Pascal Retailleau |
|---|---|
| Jazyk: | angličtina |
| Rok vydání: | 2013 |
| Předmět: | |
| Zdroj: | Acta Crystallographica Section E, Vol 69, Iss 2, Pp m108-m108 (2013) |
| Druh dokumentu: | article |
| ISSN: | 16005368 1600-5368 |
| DOI: | 10.1107/S1600536813001281 |
| Popis: | The title compound, [ZnCl2(C18H14N4O)], crystallizes with two molecules in the asymmetric unit, which differ in the tautomeric (neutral and zwitterionic) forms of the coordinating organic ligand. In both molecules, the ZnII atom adopts a distorted square–pyramidal geometry by two N and one O atoms of the Schiff base ligand and two Cl atoms acting as monodentate chloride anions. The crystal packing is stabilized by N—H...N and N—H...Cl hydrogen bonds, forming a two-dimensional network parallel to the ac plane. |
| Databáze: | Directory of Open Access Journals |
| Externí odkaz: |
|