Facile synthesis of three low-sensitivity energetic materials based on pyrimidine backbones

Autor: Ying Li, Si-wei Song, Si-tong Chen, Kang-cai Wang, Qing-hua Zhang
Jazyk: angličtina
Rok vydání: 2023
Předmět:
Zdroj: Energetic Materials Frontiers, Vol 4, Iss 1, Pp 16-23 (2023)
Druh dokumentu: article
ISSN: 2666-6472
DOI: 10.1016/j.enmf.2023.03.005
Popis: Using commercially available raw materials, novel pyrimidine-based energetic compounds were synthesized, namely N-(7-oxo-6,7-dihydro-[1,2,5]oxadiazolo[3,4-d]pyrimidin-5-yl)nitramide (1), 2,4,6-triamino-5-nitropyrimidin-1-ium nitrate (2), and 4,6-diamino-5-nitro-2-oxo-2,3-dihydropyrimidin-1-ium nitrate (3). They were fully characterized using NMR (1H and 13C), IR spectroscopy, and elemental analysis. The crystal structures of compounds 1 and 3 were determined using single-crystal X-ray diffraction. The decomposition temperatures of compounds 1–3 were measured to be 190.2 ​°C, 156.8 ​°C, and 234.6 ​°C, respectively. Their densities were tested to be 1.84, 1.85 ​g ​cm−3, and 1.81 ​g ​cm−3, respectively. They exhibited desirable insensitive properties, with impact sensitivity ≥15 ​J and friction sensitivity >360 ​N. In addition, the detonation performances of compounds 1–3 were calculated with detonation pressure of 26.9, 29.6 ​GPa, and 26.0 ​GPa, respectively; detonation velocity of 8089, 8644 ​m ​s−1, and 7996 ​m ​s−1, respectively). Simple synthetic processes and high performance make them potential candidates for low-sensitivity energetic materials.
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