Synthesis, characterization and structural studies of binuclear nickel(II) complexes derived from dihydroxybenzaldehyde thiosemicarbazones, bridged by 1,2-bis(diphenylphosphino)ethane
| Autor: | Hana B. Shawish, Mohammed Maah, Siti Nadiah Abdul Halim, Shayma A. Shaker |
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| Jazyk: | angličtina |
| Rok vydání: | 2016 |
| Předmět: | |
| Zdroj: | Arabian Journal of Chemistry, Vol 9, Iss S2, Pp S1935-S1942 (2016) |
| Druh dokumentu: | article |
| ISSN: | 1878-5352 75349078 |
| DOI: | 10.1016/j.arabjc.2014.07.012 |
| Popis: | The work described in this paper involves the synthesis and structural characterization of Ni(II) complexes derived from dihydroxybenzaldehyde thiosemicarbazones (H3L1, H3L2, H3L3, H3L4) and 1,2-bis(diphenylphosphino)ethane (dppe). Ligands and their Ni(II) complexes were characterized by elemental analysis, IR, UV–Vis, (1H, 13C, 31P) NMR, as well as magnetic moment and X-ray structure analysis. The results so obtained suggest that the thiosemicarbazone ligands behave as a tridentate ligand which were coordinated with Ni(II) ion through O, N and S atoms. Furthermore, the dppe ligand was coordinated with Ni(II) ion through the P atom. It is concluded that all Ni(II) complexes have a Square-planar geometry. |
| Databáze: | Directory of Open Access Journals |
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