Olefin hydroformylation catalysis with RuCl2(DMSO)4.

Autor: Marisela Reyes, Enrique J. Parra, Yuraima Fonseca, Bernardo Fontal, Trino Suárez, Fernando Bellandi, Ricardo R. Contreras, Isolda Romero, Lenis Prado, Pedro Cancines
Jazyk: English<br />Spanish; Castilian
Rok vydání: 2008
Předmět:
Zdroj: Avances en Química, Vol 3, Iss 1, Pp 15-20 (2008)
Druh dokumentu: article
ISSN: 1856-5301
Popis: The RuCl2(DMSO)4 complex was used as catalytic precursor in olefin hydroformylation reactions, giving good percent yield and better selectivity for linear aldehydes. The reactions were tested in homogeneous medium and biphasic organic solvent/ water systems. The substrates tried were 1-hexene, cyclohexene, 2-methyl-2-pentene, 2,3-dimethyl-2-butene; binary mixtures and synthetic naphtha and real naphtha. The activity is better for linear olefins compared with substituted olefins.
Databáze: Directory of Open Access Journals