18-Crown-6 and Dibenzo-18-crown-6 Assisted Extraction of Cesium from Water into Room Temperature Ionic Liquids and Its Correlation with Stability Constants for Cesium Complexes

Autor: Igor Vladimirovich Pletnev, Vladimir Georgyevich Krasovsky, Konstantin Ivanovich Popov, Irina Ivanovna Torocheshnikova, Svetlana Valeryevna Smirnova, Andrey Grigoryevich Vendilo, Dmitry Ivanovich Djigailo
Jazyk: angličtina
Rok vydání: 2009
Předmět:
Zdroj: Molecules, Vol 14, Iss 12, Pp 5001-5016 (2009)
Druh dokumentu: article
ISSN: 1420-3049
DOI: 10.3390/molecules14125001
Popis: The pH-profiles of the extraction of Cs+ into four conventional (1-butyl-3-methylimidazolium hexafluorophosphate and bis[trifluoromethyl)sulphonyl]imides of 1-butyl-3-methylimidazolium, 1-hexyl-3-methylimidazolium, and 1-(2-ethylhexyl)-3- methylimidazolium) and two novel (trioctylmethylammonium salicylate and tetrahexylammonium dihexylsulfosuccinate) room temperature ionic liquids have been determined both in the absence and in the presence of crown ether (18-crown-6 or dibenzo-18-crown-6). The pH-profiles of distribution ratio of crown ethers have been established in the same conditions. The relationship of cesium extraction efficiency both with the stability of its complexes with crown ethers and crown ethers’ distribution ratio has been clarified.
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