Crystal structure of (E)-2-{[(4-anilinophenyl)imino]methyl}phenol
| Autor: | Md. Serajul Haque Faizi, Turganbay S. Iskenderov, Natalia O. Sharkina |
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| Jazyk: | angličtina |
| Rok vydání: | 2015 |
| Předmět: | |
| Zdroj: | Acta Crystallographica Section E: Crystallographic Communications, Vol 71, Iss 1, Pp 28-30 (2015) |
| Druh dokumentu: | article |
| ISSN: | 2056-9890 20569890 11863838 |
| DOI: | 10.1107/S2056989014026309 |
| Popis: | The title compound, C19H16N2O, crystallized with two independent molecules (A and B) in the asymmetric unit. There is an intramolecular O—H...N hydrogen bond in each molecule with the phenol ring being inclined to the central benzene ring by 4.93 (14) and 7.12 (14)° in molecules A and B, respectively. The conformation of the two molecules differs essentially in the orientation of the terminal aminophenyl ring with respect to the central benzene ring; this dihedral angle is 50.51 (4)° in molecule A and 54.61 (14)° in molecule B. The two outer aromatic rings are inclined to one another by 51.39 (14) and 49.88 (14)° in molecules A and B, respectively. In the crystal, molecules are connected by N—H...O hydrogen bonds generating –A-B–A–B– zigzag chains extending along [010]. The chains are linked via C—H...π interactions involving neighbouring A molecules, forming slabs lying parallel to (100). |
| Databáze: | Directory of Open Access Journals |
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