'All‐In‐One' integrated ultrathin SnS2@3D multichannel carbon matrix power high‐areal–capacity lithium battery anode

Autor: Hongyi Xu, Chengxin Peng, Yuhua Yan, Fei Dong, Hao Sun, Junhe Yang, Shiyou Zheng
Jazyk: angličtina
Rok vydání: 2019
Předmět:
Zdroj: Carbon Energy, Vol 1, Iss 2, Pp 276-288 (2019)
Druh dokumentu: article
ISSN: 2637-9368
DOI: 10.1002/cey2.22
Popis: Abstract Construction of a thickness‐independent electrode with high active material mass loading is crucial for the development of high energy rechargeable lithium battery. Herein, we fabricate an all‐in‐one integrated SnS2@3D multichannel carbon matrix (SnS2@3DMCM) electrode with in‐situ growth of ultrathin SnS2 nanosheets inside the inner walls of three dimensional (3D) multichannels. The interconnected conductive carbon matrix derived from natural wood acts as an integrated porous current collector to avail the electrons transport and accommodate massive SnS2 nanosheets, while plenty of 3D aligned multichannels facilitate fast ions transport with electrode thickness‐independent even under high mass loading. As expected, the integrated SnS2@3DMCM electrode exhibits remarkable electrochemical lithium storage performance, such as exceptional high‐areal‐capacity of 6.4 mAh cm−2, high rate capability of 3 mAh cm−2 under current of 6.8 mA cm−2 (10 C), and stable cycling performance of 6.8 mA cm−2 with a high mass loading of 7 mg cm−2. The 3D integrated porous electrode constructing conveniently with the natural source paves new avenues towards future high‐performance lithium batteries.
Databáze: Directory of Open Access Journals