Bis[2-(1H-pyrazol-3-yl-κN2)pyridine-κN]dithiocyanato-κN,κS-cadmium(II)
| Autor: | Jian-Gang Li, Ying Guo, Hua Cai |
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| Jazyk: | angličtina |
| Rok vydání: | 2010 |
| Předmět: | |
| Zdroj: | Acta Crystallographica Section E, Vol 66, Iss 10, Pp m1205-m1205 (2010) |
| Druh dokumentu: | article |
| ISSN: | 16005368 1600-5368 |
| DOI: | 10.1107/S1600536810034604 |
| Popis: | The molecular structure of the mononuclear complex, [Cd(SCN)2(C8H7N3)2], contains a CdII atom in a distorted octahedral coordination defined by five N atoms from two bidentate chelate 2-(1H-pyrazol-3-yl)pyridine ligands and by one SCN− anion. The second SCN− anion provides its S atom for completion of the coordination sphere. The complex is linked to four others by N—H...N and N—H...S hydrogen-bonding interactions between the pyrazol N—H group and the terminal S and N atoms of neighbouring SCN− anions. This arrangement leads to the formation of sheets parallel to (100). Face-to-face π–π stacking interactions with shortest interplanar distances of 3.805 (2) and 3.696 (2) Å help to consolidate the crystal packing. |
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