Crystal structure of 3-({[(thiophen-2-yl)methylidene]hydrazinyl}carbonyl)pyridinium chloride dihydrate

Autor: Thangayyah Chandrasekaran, Mani Suresh, John Josephine Novina, Mohamed Khan Syed Ali Padusha, Gopalsamy Vasuki, Balasubramani Kasthuri
Jazyk: angličtina
Rok vydání: 2014
Předmět:
Zdroj: Acta Crystallographica Section E, Vol 70, Iss 9, Pp o976-o977 (2014)
Druh dokumentu: article
ISSN: 1600-5368
16005368
DOI: 10.1107/S1600536814017565
Popis: In the title compound, C11H10N3OS+·Cl−·2H2O, the organic cation exhibits a dihedral angle of 21.26 (8)° between the mean planes of the pyridine and thiophene rings, and dihedral angles of 15.11 (9) and 6.49 (9)° between the mean planes of the hydrazide moiety and the pyridine and thiophene rings, respectively. In the crystal, the organic cation, the chloride counter-anion and the two water molecules of crystallization are linked through an intricate hydrogen-bonding network consisting of O—H...O, O—H...N, N—H...Cl, C—H...Cl, C—H...O, N—H...O, O—H...Cl and C—H...S interactions that consolidate a three-dimensional network.
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