13C NMR Spectroscopic Studies of Intra- and Intermolecular Interactions of Amino Acid Derivatives and Peptide Derivatives in Solutions

Autor: Yoshikazu Hiraga, Saori Chaki, Yuri Uyama, Ryosuke Hoshide, Takumi Karaki, Daisuke Nagata, Kanji Yoshimoto, Satomi Niwayama
Jazyk: angličtina
Rok vydání: 2022
Předmět:
Zdroj: Organics, Vol 3, Iss 1, Pp 38-58 (2022)
Druh dokumentu: article
ISSN: 2673-401X
DOI: 10.3390/org3010003
Popis: 13C NMR spectroscopic investigations were conducted for various amino acid derivatives and peptides. It was observed that 13C NMR chemical shifts of the carbonyl carbons are correlated with the solvent polarities, but the extent depends on the structures. The size of the functional groups and inter- and intra-molecular hydrogen bonding appear to be the major contributors for this tendency.
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