Electrical and optical properties of hybrid polymer solar cells incorporating Au and CuO nanoparticles

Autor: Aruna P. Wanninayake, Shengyi Li, Benjamin C. Church, Nidal Abu-Zahra
Jazyk: angličtina
Rok vydání: 2015
Předmět:
Zdroj: AIMS Materials Science, Vol 3, Iss 1, Pp 35-50 (2015)
Druh dokumentu: article
ISSN: 2372-0484
DOI: 10.3934/matersci.2016.1.35
Popis: In this study, to enhance the power conversion efficiency (PCE) of the polymer solar cells (PSCs), Gold (Au) and Copper oxide nanoparticles (CuO-NPs) are incorporated into the PEDOT:PSS and P3HT/PCBM active layers respectively. PSCs with a constant CuO-NP content were fabricated with varying amounts of Au NPs. Addition of Au NPs increased the power conversion efficiency by up to 18% compared to a reference cell without Au-NPs. The short circuit current(Jsc) of the cells containing 0.06 mg of Au NPs was measured at 7.491 mA/cm2 compared to 6.484 mA/cm2 in the reference cells with 0.6 mg of CuO nanoparticles; meanwhile, the external quantum efficiency(EQE) increased from 53% to 61%, showing an enhancement of 15.1%. Au-NPs improved the charge collection at the anode, which results in higher short circuit current and fill factor. However, the strong near field surrounding Au-NPs due to localized surface plasmonic resonance (LSPR) effect is not distributed into the active layer. Instead, it is spread horizontally through the PEDOT:PSS layer, thus minimizing the light absorption in the active layer.
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