| Autor: |
Anupam Prasoon, Shaik Ghouse, Nguyen Ngan Nguyen, Hyejung Yang, Alina Müller, Chandrasekhar Naisa, Silvia Paasch, Abdallh Herbawe, Muhannad Al Aiti, Gianaurelio Cuniberti, Eike Brunner, Xinliang Feng |
| Jazyk: |
angličtina |
| Rok vydání: |
2024 |
| Předmět: |
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| Zdroj: |
Nature Communications, Vol 15, Iss 1, Pp 1-10 (2024) |
| Druh dokumentu: |
article |
| ISSN: |
2041-1723 |
| DOI: |
10.1038/s41467-024-54962-z |
| Popis: |
Abstract The chemistry of the on-water surface, characterized by enhanced reactivity, distinct selectivity, and confined reaction geometry, offers significant potential for chemical and materials syntheses. However, the utilization of on-water surface synthesis is currently limited by the requirement for a stable air-water interface, which restricts its broader synthetic applications. In this work, we present a approach that mimics on-water surface chemistry using micelles. This method involves the self-assembly of charged surfactant molecules beyond their critical micelle concentration (CMC), forming micellar structures that simulate the air-water interface. This creates an environment conducive to chemical reactions, featuring a hydrophobic core and surrounding water layer. Utilizing such mimicking on-water surface with the assembly of porphyrin-based monomers featuring distinct confined geometry and preferential orientations, we achieve reactivity and selectivity (≥99%) in fourteen different reversible and irreversible chemical reactions. Extending the versatility of this approach, we further demonstrate its applicability to two-dimensional (2D) polymerization on micellar interfaces, successfully achieving the aqueous synthesis of crystalline 2D polymer thin layers. This strategy significantly broadens the accessibility of on-water surface chemistry for a wide range of chemical syntheses. |
| Databáze: |
Directory of Open Access Journals |
| Externí odkaz: |
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