| Autor: |
Qutaiba Abu-Salem, Mohammad K. Harb, Cäcilia Maichle-Mößmer, Manfred Steimann, Wolfgang Voelter |
| Jazyk: |
angličtina |
| Rok vydání: |
2017 |
| Předmět: |
|
| Zdroj: |
Arabian Journal of Chemistry, Vol 10, Iss S2, Pp S3883-S3888 (2017) |
| Druh dokumentu: |
article |
| ISSN: |
1878-5352 |
| DOI: |
10.1016/j.arabjc.2014.05.027 |
| Popis: |
The gold(I) complex [Au(DMC)(PPh3)] (1) (DMC = 1,3-dimethylcyanurate) was synthesized and characterized by elemental analysis, FT-IR, 1H, 13C, 31P NMR and FAB mass spectroscopies. The structure of the complex was determined by X-ray diffraction and crystallizes in the triclinic space group P−1 with Z = 2. The gold(I) ion in complex 1 is coordinated by DMC ligand and PPh3 ligand, resulting in a slightly distorted linear structure. Molecules of 1 are connected via intermolecular CH···O hydrogen bonds, which lead to the formation of supramolecular network. Other intramolecular interactions which include Au···O contacts [Au···O25 3.045(1) and Au···O29 3.164(1)Å] were observed. |
| Databáze: |
Directory of Open Access Journals |
| Externí odkaz: |
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