Pressure-induced liquid-liquid transition in a family of ionic materials

Autor: Zaneta Wojnarowska, Shinian Cheng, Beibei Yao, Malgorzata Swadzba-Kwasny, Shannon McLaughlin, Anne McGrogan, Yoan Delavoux, Marian Paluch
Jazyk: angličtina
Rok vydání: 2022
Předmět:
Zdroj: Nature Communications, Vol 13, Iss 1, Pp 1-10 (2022)
Druh dokumentu: article
ISSN: 2041-1723
DOI: 10.1038/s41467-022-29021-0
Popis: Liquid−liquid transitions (LLTs) have been reported for some molecular systems but are difficult to observe under high pressure conditions. Here the authors report and characterize a first-order LLT in a series of ionic liquids containing the trihexyl(tetradecyl)phosphonium cation and anions of different sizes and shapes, using calorimetric and dielectric measurements.
Databáze: Directory of Open Access Journals