Bis(ethylenediammonium) μ-ethylenediaminetetraacetato-1κ3O,N,O′:2κ3O′′,N′,O′′′-bis[trioxidomolybdate(VI)] tetrahydrate
| Autor: | Lamine Yaffa, Dame Seye, Antoine Blaise Kama, Assane Toure, Cheikh Abdoul Khadir Diop |
|---|---|
| Jazyk: | angličtina |
| Rok vydání: | 2024 |
| Předmět: | |
| Zdroj: | IUCrData, Vol 9, Iss 7, p x240667 (2024) |
| Druh dokumentu: | article |
| ISSN: | 2414-3146 24143146 |
| DOI: | 10.1107/S2414314624006679 |
| Popis: | The title compound, (C2H10N2)2[(C10H12N2O8)(MoO3)2]·4H2O, which crystallizes in the monoclinic C2/c space group, was obtained by mixing molybdenum oxide, ethylenediamine and ethylenediaminetetraacetic acid (H4edta) in a 2:4:1 ratio. The complex anion contains two MoO3 units bridged by an edta4− anion. The midpoint of the central C—C bond of the edta4− anion is located on a crystallographic inversion centre. The independent Mo atom is tridentately coordinated by a nitrogen atom and two carboxylate groups of the edta4− ligand, together with the three oxo ligands, producing a distorted octahedral coordination environment. In the three-dimensional supramolecular crystal structure, the dinuclear anions, the organoammonium counter-ions and the solvent water molecules are linked by N—H...Ow, N—H...Oedta and O—H...O hydrogen bonds. |
| Databáze: | Directory of Open Access Journals |
| Externí odkaz: |
|