All-Polymer Piezo-Composites for Scalable Energy Harvesting and Sensing Devices

Autor: George-Theodor Stiubianu, Adrian Bele, Alexandra Bargan, Violeta Otilia Potolinca, Mihai Asandulesa, Codrin Tugui, Vasile Tiron, Corneliu Hamciuc, Mihaela Dascalu, Maria Cazacu
Jazyk: angličtina
Rok vydání: 2022
Předmět:
Zdroj: Molecules, Vol 27, Iss 23, p 8524 (2022)
Druh dokumentu: article
ISSN: 1420-3049
DOI: 10.3390/molecules27238524
Popis: Silicone elastomer composites with piezoelectric properties, conferred by incorporated polyimide copolymers, with pressure sensors similar to human skin and kinetic energy harvester capabilities, were developed as thin film (2). The piezoelectric properties of the tested materials were determined using a dynamic mode of piezoelectric force microscopy. These composite materials bring together polydimethylsiloxane polymers with customized poly(siloxane-imide) copolymers (2–20 wt% relative to siloxanes), with siloxane segments inserted into the structure to ensure the compatibility of the components. The morphology of the materials as free-standing films was studied by SEM and AFM, revealing separated phases for higher polyimide concentration (10, 20 wt%). The composites show dielectric behavior with a low loss (−1) and a relative permittivity superior (3–4) to pure siloxane within a 0.1–106 Hz range. The composite in the form of a thin film can generate up to 750 mV under contact with a 30 g steel ball dropped from 10 cm high. This capability to convert a pressure signal into a direct current for the tested device has potential for applications in self-powered sensors and kinetic energy-harvesting applications. Furthermore, the materials preserve the known electromechanical properties of pure polysiloxane, with lateral strain actuation values of up to 6.2% at 28.9 V/μm.
Databáze: Directory of Open Access Journals
Nepřihlášeným uživatelům se plný text nezobrazuje