| Autor: |
SANJA GRGURIC-SIPKA, MOHAMED AL ARBI M. ALSHTEWI, DEJAN JEREMIC, GORAN N. KALUDJEROVIC, SANTIAGO GÓMEZ-RUIZ, ZELJKO ZIZAK, ZORICA JURANIC, TIBOR J. SABO |
| Jazyk: |
angličtina |
| Rok vydání: |
2008 |
| Předmět: |
|
| Zdroj: |
Journal of the Serbian Chemical Society, Vol 73, Iss 6, Pp 619-630 (2008) |
| Druh dokumentu: |
article |
| ISSN: |
0352-5139 |
| Popis: |
Two new p-cymene ruthenium(II) complexes containing as additional ligands N-methylpiperazine ([(η6-p-cymene)RuCl2(CH3NH(CH2)4NH)]PF6, complex 1) or vitamin K3-thiosemicarbazone ([(η6-p-cymene)RuCl2(K3tsc)], complex 2) were synthesized starting from [(η6-p-cymene)2RuCl2]2 and the corresponding ligand. The complexes were characterized by elemental analysis, IR, electronic absorption and NMR spectroscopy. The X-ray crystal structure determination of complex 1 revealed “piano-stool” geometry. The differences in the cytotoxic activity of the two complexes are discussed in terms of the ligand present. |
| Databáze: |
Directory of Open Access Journals |
| Externí odkaz: |
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